PbO2/rGO Electrode as a Superior and Efficient Anode in Electrocatalytic Degradation of Safranine-O

Aryani, Titin, Aryani, Titin and Roto, Roto and Mudasir, Mudasir (2024) PbO2/rGO Electrode as a Superior and Efficient Anode in Electrocatalytic Degradation of Safranine-O. Bulletin of Chemical Reaction Engineering and Catalysis, 19 (3). pp. 480-499. ISSN 19782993

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Abstract

The electrocatalytic degradation method with PbO2/rGO electrode (anode) was chosen to treat Safranine-O waste because it was cheap and environmentally friendly. This research aimed to study the electrocatalytic efficiency of PbO2/rGO working electrode in Safranine-O removal. In this research, rGO and PbO2/rGO electrodes were synthesized and applied to Safranine-O removal through electrochemical degradation. The characterization results of the morphology of rGO are in the form of a layered structure and have the atomic composition of C (82.87%) and O (17.13%). The characterization results of PbO2/rGO are uniform particles with gaps/pores that appear relatively large. The rGO particles in the form of sheets (layers) seem to be distributed on the surface of PbO2. PbO2/rGO electrode has the atomic composition of C (87.24%), O (9.03), and Pb (3.73). The application of PbO2/rGO anode to the electrochemical degradation of Safranine-O showed good performance. It was able to perform dye removal (DE%), as well as a decrease in BOD and COD values up to >95% within 10 minutes at a concentration of 20 ppm. Application on real waste also showed the ability of dye removal, COD, and BOD reduction up to >95%. Coating or modifying the PbO2 anode with rGO can reduce the dissolution of Pb2+ ions in the solution during the electrochemical degradation. This study concluded that the PbO2/rGO electrode has improved the efficiency in Safranine-O degradation.

Item Type: Article
Uncontrolled Keywords: Dye; Electrochemical degradation; Lead Dioxide; rGO; Waste
Subjects: Q Science > QD Chemistry
Divisions: Faculty of Mathematics and Natural Sciences > Chemistry Department
Depositing User: Wiyarsih Wiyarsih
Date Deposited: 13 Mar 2025 04:20
Last Modified: 13 Mar 2025 04:20
URI: https://ir.lib.ugm.ac.id/id/eprint/15738

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