Umami, Muhammad Rizza and Siswanta, Dwi and Mudasir, Mudasir (2023) Solid-Phase Extraction of Pb(II) Using Glutaraldehyde Crosslinked Chitosan/Carboxymethyl Cellulose. Malaysian Journal of Chemistry, 25 (4). pp. 62-72. ISSN 15112292
Solid-phase extraction.pdf - Published Version
Restricted to Registered users only
Download (481kB) | Request a copy
Abstract
Glutaraldehyde-crosslinked chitosan/carboxymethyl cellulose was synthesized as a sorbent for the solid-phase extraction (SPE) of Pb ions. This study optimized the SPE method for Pb2+ preconcentration. SPE parameters such as pH, sample concentration, loading and eluting flow rates, and reusability were investigated. The Pb2+ concentration retained in the sorbent was analysed using AAS (atomic absorption spectrometry), while the sorbent was characterized using FT-IR (Fourier transform infrared) spectroscopy and SEM-EDX (scanning electron microscope-energy dispersive x-ray). The optimum parameters for SPE were pH 6, an initial Pb concentration of 10 mg L-1 and flow rates for both loading and elution of 9 mL min-1. The highest efficiency achieved under these optimum conditions was 98.98 %. However, this efficiency reduced with repeated sorbent usage to 82.34 % in the second cycle and 40.22 % in the fifth cycle.
Item Type: | Article |
---|---|
Uncontrolled Keywords: | carboxymethyl cellulose; glutaraldehyde; crosslinking; solid-phase |
Subjects: | Q Science > QD Chemistry |
Divisions: | Faculty of Mathematics and Natural Sciences > Chemistry Department |
Depositing User: | Wiyarsih Wiyarsih |
Date Deposited: | 15 Aug 2024 08:05 |
Last Modified: | 15 Aug 2024 08:05 |
URI: | https://ir.lib.ugm.ac.id/id/eprint/3045 |