Lestari, Diana and Wahyuningsih, Tutik Dwi and Purwono, Bambang (2023) Colorimetric Chemosensor for Sulfide Anion Detection Based on Symmetrical Nitrovanillin Azine. Indonesian Journal of Chemistry, 23 (1). pp. 12-20. ISSN 14119420
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Abstract
The nitrovanillin azine (NA) has been successfully synthesized and examined as a colorimetric chemosensor for sulfide anion detection. The NA was synthesized using two steps reaction. Vanillin was reacted with concentrated nitric acid to form 5-nitrovanillin (NV) then the NV was condensed with hydrazine hydrate to produce the NA. The NA was obtained and fully elucidated by FTIR,1H-NMR,13C-NMR, and GC-MS spectrometer. The NA activity for anionic chemosensor was then carried out on several anions such as F⁻, Cl⁻, Br⁻, I⁻, S2⁻, CN⁻, HCO3⁻, AcO⁻, H2PO4⁻, N3⁻, NO2⁻, SCN⁻, ClO3⁻, and NO3⁻. The chemosensor tests showed NA was only selective for S2− in DMF:HEPES buffer (9:1, v/v, 10 mM, pH = 7.4) giving color change from light yellow to dark green. The LOD value was 1.43 × 10−5 M and the interaction model of NA-S2− indicated deprotonation mode between the-OH group with sulfide anion in a ratio of 1:1. The NA chemosensor can be applied for qualitatively analysis of sulfide anion using filter paper strips and quantitatively analysis of sulfide anion in tap water.
Item Type: | Article |
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Uncontrolled Keywords: | 5-nitrovanillin; azine; chemosensor; colorimetric; hydrazine |
Subjects: | Q Science > QD Chemistry |
Divisions: | Faculty of Mathematics and Natural Sciences > Chemistry Department |
Depositing User: | Ismu WIDARTO |
Date Deposited: | 20 Sep 2024 07:09 |
Last Modified: | 20 Sep 2024 07:09 |
URI: | https://ir.lib.ugm.ac.id/id/eprint/7378 |