Oshima, Tatsuya and Asano, Tokiya and Ishibashi, Tatsuya and Ohe, Kaoru and Ohto, Keisuke and Jumina, Jumina (2023) Extraction of Metal Ions Using a Calix[4]arene Carboxylic Acid Derivative in Aromatic Ethers. Solvent Extraction Research and Development, Japan, 30 (1). pp. 59-69. ISSN 13417215
107. Extraction-of-Metal-Ions-Using-a-Calix4arene-Carboxylic-Acid-Derivative-in-Aromatic-EthersSolvent-Extraction-Research-and-Development-Japan.pdf - Published Version
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Abstract
If calixarenes can be dissolved in a relatively safe non-halogen solvent, they can be used in a liquid-liquid extraction process suitable for mass processing. In the present study, extraction behavior of metal ions using a calix[4]arene carboxylic acid derivative (tOct[4]CH2COOH) dissolved in aromatic ethers was investigated. The solubility of tOct[4]CH2COOH in aromatic ethers decreases with increase of the length of aliphatic side chain of the ethers. The solubility of tOct[4]CH2COOH in 1-butoxybenzene (BB) was 28.0 mmol/L, which is smaller than that in chloroform but is higher than those in hexane and toluene. Divalent metal ions Mn(II), Co(II), Ni(II), Cu(II), Zn(II), and Pb(II) were extracted using tOct[4]CH2COOH in BB through proton exchange reaction at similar pH range in toluene, which is higher than that in chloroform. The extraction reaction of Cu(II) using tOct[4]CH2COOH in BB was determined by slope analysis and loading test. The stoichiometry between tOct[4]CH2COOH and Cu(II) was 2:1.
Item Type: | Article |
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Subjects: | Q Science > QD Chemistry |
Divisions: | Faculty of Mathematics and Natural Sciences > Chemistry Department |
Depositing User: | Ismu WIDARTO |
Date Deposited: | 20 Sep 2024 08:42 |
Last Modified: | 20 Sep 2024 08:42 |
URI: | https://ir.lib.ugm.ac.id/id/eprint/7379 |