Adsorption of silver(I) on dithizone-immobilized coal fly ash

Shofwunnada, S. and Aprilita, Nurul Hidayat and Mudasir, Mudasir (2021) Adsorption of silver(I) on dithizone-immobilized coal fly ash. Key Engineering Materials, 884 KE. 17 – 24. ISSN 10139826

Full text not available from this repository. (Request a copy)

Abstract

Adsorption of Ag(I) on dithizone-immobilized coal fly ash (Dtz-CFA) from PT Madukismo Factory, Yogyakarta, Indonesia has been investigated. Immobilization of dithizone on activated coal fly ash (Act-CFA) was done by stirring the mixture of two precursors in toluene medium at 50o C for 16 h. Parameters influencing adsorption of Ag(I) such as pH of solution, contact time and initial concentration of Ag(I) ions were optimized. FT-IR and XRD characteriztions show that the surface of fly ash has successfully immobilized by dithizone. The optimum conditions for Ag(I) adsorption are reached at pH 6, contact time of 45 min and initial concentration of 100 mg g-1 . The ability of Dtz-CFA to adsorb Ag(I) metal ions significantly increases as compared to that of Act-CFA. Kinetic and isotherm adsorption studies suggest that adsoption of Ag(I) using both Act-CFA and Dtz-CFA follows a second-order pseudo reaction and Langmuir isotherm model, respectively. These results indicate that Dtz-CFA may be used as prospective adsorbent for removing Ag(I) ion. © 2021 Trans Tech Publications Ltd, Switzerland.

Item Type: Article
Additional Information: Cited by: 2
Uncontrolled Keywords: Coal; Coal ash; Fly ash; Isotherms; Metal ions; Metals; Silver compounds; Activated coals; Coal fly ash; Contact time; Dithizone; Immobilisation; Indonesia; Initial concentration; Isotherm adsorption; Optimum conditions; XRD; Adsorption
Subjects: Q Science > QD Chemistry
Divisions: Faculty of Mathematics and Natural Sciences > Chemistry Department
Depositing User: Sri JUNANDI
Date Deposited: 05 Oct 2024 13:16
Last Modified: 05 Oct 2024 13:16
URI: https://ir.lib.ugm.ac.id/id/eprint/8776

Actions (login required)

View Item
View Item