Preliminary Investigation of Organocatalyst Activity Based on <i>C</i>-Arylcalix[4]-2-Methylresorcinarene Sulfonic Acid Materials for Biodiesel Production

Jumina, Jumina and Amalina, Ifa and Triono, Sugeng and Kurniawan, Yehezkiel Steven and Priastomo, Yoga and Ohto, Keisuke and Yamin, Bohari M. (2021) Preliminary Investigation of Organocatalyst Activity Based on <i>C</i>-Arylcalix[4]-2-Methylresorcinarene Sulfonic Acid Materials for Biodiesel Production. BULLETIN OF THE KOREAN CHEMICAL SOCIETY, 42 (3). pp. 403-409. ISSN 0253-2964

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Abstract

At present, biodiesel remains an untapped fuel source while crude oil reserves are being depleted. Extensive efforts are necessary to achieve efficient biodiesel production, but catalytic activity in methyl palmitate production remains unsatisfactory. In this study, we report the synthesis and organocatalyst activity of C-arylcalix[4]-2-methylresorcinarene sulfonic acids for biodiesel production. The presence of a methyl group on an aromatic ring is expected to disturb the intramolecular hydrogen bonds; thus, each hydroxyl group could be utilized for the catalytic process. C-arylcalix[4]-2-methylresorcinarene sulfonic acids were prepared from cyclocondensation and sulfonation reactions yielding compounds 1-6 at rates of 66.7%-86.6%. By evaluating the organocatalytic activity of the C-arylcalix[4]-2-methylresorcinarene sulfonic acids, we found that 4 mol% of compound 5 exhibited the highest yield (97.8%) of methyl palmitate at 338 K for 6-h reaction time, which is remarkable. These findings show that C-arylcalix[4]-2-methylresorcinarene sulfonic acids are promising heterogeneous catalyst materials for biodiesel production.

Item Type: Article
Uncontrolled Keywords: Organocatalyst; Calix[4]-2-methylresorcinarene; Sulfonic acid; Biodiesel; Methyl palmitate
Subjects: Q Science > QD Chemistry
Divisions: Faculty of Mathematics and Natural Sciences > Chemistry Department
Depositing User: Sri JUNANDI
Date Deposited: 15 Oct 2024 07:03
Last Modified: 15 Oct 2024 07:03
URI: https://ir.lib.ugm.ac.id/id/eprint/9339

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